# Coffee, tea, and Joulies

I really liked Marco Arment’s post last week on how he tested his first set of Coffee Joulies. Joulies are the little bean-shaped things that are supposed to cool your coffee quickly to the optimal drinking temperature and keep it there for a long time. Their manufacture was funded by a very successful Kickstarter project that Marco talked about on an early episode of his Build & Analyze podcast.

The upshot of Marco’s testing is that the Joulies don’t work very well. After reading his post I had some ideas about why that’s so, but I didn’t want to write it up until I heard him discuss his testing on the most recent B&A episode. Now that I have, it’s time to inflict my thoughts on you.

Let me start by saying I have virtually no interest in coffee itself and find all discussions of the perfect roasting, grinding, brewing, etc. unbelievably tedious. And not just because I’m a tea drinker. Although I have my likes and dislikes, I’m not in the Cult of Tea, insisting on precise water temperatures and steeping times. My position on tea brewing closely parallels Arlo’s:

Update 8/16/11
Apparently, sugar in one’s tea isn’t as déclassé in the UK as Radio 4 has led me to believe. I blame Laurie Taylor for my cultural misunderstanding.

So anyway, my interest in Joulies is purely academic. It’s an intriguing bit of engineering, trying to take advantage of certain physical properties of a material to make a clever and useful product.

The physical property at issue is the heat of fusion, the heat input required to change a material from solid to liquid. You may remember from physics class a graph like this:

This one was taken from the second edition of Sears and Zemansky’s University Physics1 and shows how the temperature of a quantity of water would change if it were given a constant rate of heat input. In the solid (ice) phase, the temperature increases at a steady rate until it hits 0° C. At this point, the heat goes into changing the phase from solid to liquid, and the temperature doesn’t increase until all the ice is melted. Then the temperature rises again at a steady rate until a similar thing happens at the boiling point.

The same graph can also be used to describe the temperature changes as heat is extracted from water, but in this case time would march from right to left instead of left to right.

This is the behavior Joulies are trying to capture, except that the material in Joulies has its solid/liquid phase transition at about 60° C (140° F) instead of 0° C. I don’t know what the material inside the Joulies is, but The Handbook of Chemistry and Physics lists many organic materials with melting points at or near 60° C. The Joulies website says only that it’s a lightweight, food-grade material surrounded by a thin stainless steel shell.

Marco’s tests, though, show that a mug of coffee with Joulies cools at at rate that’s almost the same as a mug with no Joulies.2 Here’s his graph of one comparison test:

The faster cooling early on is no surprise. The Joulies are initially at room temperature and must absorb heat from the coffee to rise to its temperature. Anything you put in the mug would—qualitatively, at least—behave the same way.

The slowdown in cooling that we see in the green line between 150° and 140° is certainly due to the Joulies trying to hold to a constant temperature during the phase change. But by the time the coffee is about 130°, the two mugs are cooling at an almost identical rate.

So the Joulies have definitely had an effect in this test, but it’s pretty small. The temperature difference between the coffees is never more than about 5°.

This was actually the best test for the Joulies. In the test performed in ceramic cups, the coffee temperatures were practically indistinguishable.3

OK, so why don’t they work better? Let’s go back to the fundamentals.

The rate at which cooling occurs depends on:

1. The temperature difference between the hot item(s) and the environment.
2. The insulating characteristics of the container.
3. The heat content of the hot item(s).

The first two are the same for coffee with and without Joulies, so we need to focus on the third.

The heat content of the coffee itself is governed by the specific heat of water, which is by definition 1 calorie per gram per degree Celsius. On a volumetric basis, 1 calorie of heat is required to change 1 cubic centimeter of coffee by 1° C.

For a cup or mug with Joulies, some volume of coffee is replaced by the shiny beans, so we have to compare their heat content, which comes from both the stainless steel shell and the mystery material within, to that of the coffee.

The stainless steel shell of the Joulie has a specific heat of only 0.119 cal/g∙°C, but stainless steel is 8 times as dense as water, so on a volumetric basis 0.955 calories of heat is required to to change 1 cc of stainless steel by 1° C. Because this is so close to the value for the coffee itself, we can say that the replacement of a certain volume of coffee in our cup with stainless steel has no significant effect on the total heat content.

Which leaves the mystery material. Because its job is to keep the coffee near 140°—the mystery material’s melting/freezing point—the critical property is its heat of fusion. A high heat of fusion is desirable because that will cause it to release a lot of heat into the coffee as it solidifies, keeping the coffee warmer longer.

My guess is that the material inside the Joulies just doesn’t have a high enough heat of fusion to work the way you’d like it to. The necessity of using a safe, food-grade material with a melting/freezing point near 140° probably put a severe restriction on the compounds the Joulies’ inventors could choose from. There are probably some really toxic substances that would do a better job of keeping your coffee warm, but they weren’t suitable, even inside the stainless steel shell.

That’s it for the material. I can thing of one other factor that may be limiting the Joulies’ effectiveness: a lack of mixing. Even if the Joulies are staying close to 140°, the coffee that’s not in contact with the Joulies isn’t being warmed by them. There will be convection currents in the coffee, but they may not be strong enough to do a good job of mixing.

So we have a product that sounds like it should work because it’s based on real physical behavior. It has a cute and scientifically resonant name. Unfortunately, it doesn’t work much better than good insulated mug. Too bad.

Or maybe not. The Joulie inventors seem to be doing well. The Kickstarter project raised about 30 times the money they were asking for, and Marco is certain that Joulies will sell despite his tests. He’s probably right—coffee fanatics are delusional. Here’s a rave review by a coffee blogger who declares the product a success after a laughable test:

We brewed the Hario V60 using twenty grams of coffee and three hundred milliliters of water at around 200 degrees. 30 second bloom, 2:00 total pour, 2:45 brew time. We added three Coffee Joulies to the ten ounce cup of coffee and watched as the thermometer slowly crept down. When the coffee had finished brewing through the V60 it reached a temperature of around 155 degrees – totally drinkable and absolutely delicious. The coffee went down in temperature and hit 140 degrees at around five minutes, staying there for quite some time.

“Quite some time.” Lord Kelvin would be proud.

1. © 1955. It was my father’s. The book is now in its 13th edition, and the original authors’ names are now part of the title. I like my copy better.

2. I say his tests show this because I think we can trust his results. It’s possible that he screwed up in some way, but I doubt it. His descriptions indicate that he took a reasonable amount of care in his measurements and that he used the Joulies as they’re intended to be used.

3. Marco actually did two tests in ceramic cups, but the second test was so heavily and unrealistically weighted in favor of the Joulies I’m discounting it. Even in that test, the difference between the two cups was significant only in the early stages of the test.

## 18 Responses to “Coffee, tea, and Joulies”

1. Grant says:

Nice explanation of what is going on with this ridiculous product. The amusing thing about all of this is that coffee is only properly fresh for about 10 minutes after brewing regardless of the temperature. So these are for those special breed of fanatics that are fanatical less about what is really going on and more about what products they are using. Joulies could be thought of as a “distraction free” coffee product, keeping your coffee warm without regard to freshness for “quite some time”.

2. Sugar’s hardly controversial in Britain. In fact, we’re notorious for the stuff. A tea with neither milk nor sugar is suspiciously continental.

3. Milk yes, but I was under the impression that sugar was considered a working class thing.

4. Perhaps too much sugar is. That, or a sign of old age: grannies and sickly-sweet tea are an accurate national cliché. And don’t forget the plate of buttery scones, or in Scotland, Tunnock’s wafers.

Tea here is what coffee is to America: everyone’s invited, besides those joyless souls and those inflicted with an inhumane allergy or diet. And there’s no rule against liking both. Which lets me get my dig in against Marco: why the filter? That’s just scarcely coffee.

All too obvious I’m on my way to dinner. Or, another Scottishism: “tea”. Yes, it’s that ingrained here.

5. DirkKS says:

Lack of mixing, poor thermal conductivity, and lack of surface area. An aluminum surround, with fins, would work much better than those stainless steel pebbles. But who wants to drop a heat sink into their coffee?

6. DirkKS says:

Also, remember point 1 -the temperature difference between the hot item and the environment — applies to the coffee-Joulie interface as well. The goal is to maintain the coffee in a very narrow temperature range, and that’s just hard. A 5° - 10° difference between the Joulies and the coffee isn’t going to drive much heat exchange; the difference in temperature between the coffee and the air is much larger.

7. Charles says:

Which got me to thinking that a thermally insulated mug, with a third phase-change layer would do the trick. wouldn’t it?

Charles

8. Today I bought a copy of Sears and Zemansky’s University Physics (12th edition). I feel a bit more confident on that purchase for some odd reason now. And to DirkKs’s earlier comment regarding point 1: this explains the greater delta in the slopes while the Joulies helped cool the coffee. The difference between room temperature and the 200 degree coffee is far greater than the difference between the 140 degree Joulies and the 140 (or less) degree coffee. If you cared more about having cooler coffee, faster than keeping it war longer, the Joulies may be more useful.

9. Huh. I had assumed the problem had to do with the stainless steel - that it was too effective of a resistor. I’ve been hoping that the Joulies would eventually switch to aluminum or something, but it sounds like that wouldn’t help. Or would it?

10. @Jemaleddin

Nope. The metal shell isn’t the fundamental problem. What’s really the matter is the scale of heat loss through (and above) the cup. Insulation is the answer.

Might I suggest someone try another project on Kickstarter? A vacuum walled “thermos” cup disguised as ordinary kitchenware.

Joulies look cool but are ineffective. Travel mugs are effective but don’t look cool. Somewhere, between them, lies potential.

11. I don’t think thermal conductivity of the shell is an issue for two reasons:

1. The shell is pretty thin. Based on some information in the Joulies FAQ, I estimate the volume of the shell to be no more than about 10% of the total volume of a Joulie. The thinner the shell, the faster the conduction of heat through it.
2. While the thermal conductivity of stainless steel (16 W/m·K) is only one-fifteenth that of aluminum (250 W/m·K), it’s over 25 times that of water (0.6 W/m·K). So the heat should zip through the shell and get to the phase change material pretty quickly.
12. Will,

University Physics is one of my favorite references because of the clarity of Sears and Zemansky’s writing. If the current authors have kept to that tradition, you have a book (or books—it’s mulitivolume now, isn’t it?) you’ll enjoy for decades.

13. Stuart says:

In the UK, I suppose sugar could be considered working class. I know whenever we have work done it’s often accompanied by tea with at least two sugars, but it’s hardly frowned upon.

Growing up, I just remember that it was like passing into adulthood when you stopped putting sugar in tea and coffee.

14. BtheT says:

The material inside the metal is almost certainly paraffin wax.

It has exactly the same properties that would be ideal in this application: http://en.wikipedia.org/wiki/Paraffin

15. I think BtheT has hit the nail on the head!

Paraffin wax is one of those vaguely defined materials, like gasoline and diesel fuel, that is usually a mixture of compounds in the alkane family (see the Wikipedia article BtheT linked to). Alkanes are the elementary hydrocarbons you learned about in chemistry class: methane (CH4), propane (C3H8), and octane (C8H18) are probably the ones you drew pictures or made ball-and-stick models of. The alkanes in paraffin wax are in the same family but have many more carbons.

Paraffin wax is (or can be) food grade, and its melting point can be “tuned” to about 140°. It’s heat of fusion is about 50 cal/g, or about 45 cal/cc on a volumetric basis. This is a decent heat of fusion (water/ice is 80 cal/g), but is unlikely to retard the temperature drop significantly unless it makes up so much of the volume that you’re left with much less coffee.

If the material is paraffin wax, there’s one more thing to consider. In my experience, mixtures of compounds don’t have a well-defined melting point; they melt in stages over a range of temperatures corresponding to the melting points of their constituents. The upshot is that paraffin wax won’t “hold” at a particular temperature like water does in the graph above, it’ll drift over a range of temperatures.

16. Clark says:

Ah - paraffin wax. The traditional sealer of jams and jellies for people of a certain age. (i.e. dying off fast) I still have fond memories of people sealing mason bottles like that although the lids with the rubber you put on hot and that form a “semi-vacuum” once the air cools did in the need for paraffin.

My dad used to love chewing paraffin wax off the top of such bottles my grandmother would send. He liked it better than gum.

While food grade industrial paraffin is reasonably consistent you’re right about there being some inconsistencies. There are various “contaminants” that will affect the thermodynamic properties in various places.

17. Fernando Cueva says:

Has any of you considered that the volume occupied by the Joulies is volume lost for coffee? so, not only are these little things useless, they also steal your pleasure!

18. i told a friend these wouldn’t work. the “dave” demonstration on the joulies website is an intentionally deceptive demonstration that proves none of what is promised. different amounts of boiling water were used, and coffee is not boiling hot, so the difference is exagerated, and more energy is being given to the joulies. the different cooling temps and times were ignored after getting to 140 f. if this was what they counted on, informercials in the early hours would be a better way of marketing them.